Product ID:ETHYLENE GLYCOL,TECHNICAL-MIL-E-9500B
MSDS Date:08/24/1989
FSC:6810
NIIN:00-006-4205
MSDS Number: BRFKS

PHIPPS PRODUCTS CORP.

186 LINCOLN STREET SUITE 502
BOSTON, MA 02111-2403
US

Emergency Phone: COMPANY OUT OF BUSINESS

Info Phone: COMPANY OUT OF BUSINESS

Preparer: DGSC-SSH

Cage: 86511

PHIPPS PRODUCTS CORP

BOSTON, MA 02111-2403 US

Telephone: OUT OF BUSINESS

Cage: 86511

ETHYLENE GLYCOL (SARA III)

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: <99.9%

OSHA PEL C 50 PPM

ACGIH TLV: C 50 PPM,VAPOR; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

1,4-DIOXANE (DIETHYLENE DIOXIDE) (SARA III)

CAS: 123-91-1

RTECS: JG8225000

Fraction By Weight: 0.0015%

OSHA PEL S, 100 PPM

ACGIH TLV: S, 25 PPM; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE OXIDE (SARA III)

CAS: 75-21-8

RTECS: KX2450000

Fraction By Weight: 0.0001%

OSHA PEL 1 PPM; SEE 1910.1047

ACGIH TLV: 1 PPM, A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

LD50 LC50 Mixture:LD50 (ORAL RAT) IS 4G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:IRRITATION OF
EYES,SKIN,RESPIRATORY OR G.I.TRACTS;CNS EFFECTS LIKE
HEADACHE,DIZZINESS,NAUSEA,VOMITING AND POSSIBLE
UNCONSCIOUSNESS;FATAL IF INGESTED.CHRONIC:DRYING OF SKIN,DEFATTING
OR DERMATITI S/ALLERGIC REACTION OR SENSITIZITON,LIVER AND KIDNEY
DAMAGE,CNS DEPRESSION.
Explanation of Carcinogenicity:ETHYLENE GLYCOL HAS SHOWN TO PRODUCE
DOSE- RELATED TERATOGENIC EFFECTS IN RATS AND MICE WHEN GIVEN BY
GAVAGE.
Effects of Overexposure:CNS EFFECTS ARE
HEADACHE,DIZZINESS,NAUSEA,VOMITING,POSSIBLE
UNCONSCIOUSNESS.SKIN:DRYING,DERMATITIS.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR
RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING.
GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER
FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:
REMOV E CONTAMINATED CLOTHING. WASH WITH SOAPAND WATER. IF
IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE
VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE
MEDICAL ATTENTION.

Flash Point Method:TCC
Flash Point:241F,116C
Lower Limits:3.2
Upper Limits:15.3
Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER
FOG.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:NONE.

Spill Release Procedures:USE PROPER PERSONAL PROTECTION;CONTAIN FREE
MATERIAL IF POSSIBLE;USE SUITABLE INERT ABSORBENT MATERIAL AND
RECOVER FOR PROPER DISPOSAL IN AN APPROVED CONTAINER.
Neutralizing Agent:NOT APPLICABLE.

Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT
CONTAINERS FROM PHYSICAL DAMAGE.
Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID
PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES.
USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING.

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC
VAPROR/MIST IF ABOVE PEL/TLV OR SCBA IN AN ENCLOSED AREA.
Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV.
Protective Gloves:NEOPRENE, NITRILE, OR NATURAL RUBBER.
Eye Protection:SAFETY GOGGLES WITH FACE SHIELD
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER,WORK
CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO
NOT BREATHE VAPORS OR MISTS.DO NOT TAKE INTERNALLY.

HCC:V5
Boiling Pt:>197.2C, 387.F
Melt/Freeze Pt:=-12.6C, 9.F
Vapor Pres:0.08
Vapor Density:2.1
Spec Gravity:1.115
Evaporation Rate & Reference:0.01(N-BUTYL ACETATE = 1)
Solubility in Water:100 %(COMPLETE)
Appearance and Odor:COLORLESS LIQUID,MILD ODOR

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS,STRONG ACIDS,STRONG BASES AND MATERIAL REACTIVE
WITH HYDROXYL COMPOUNDS.
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND
OTHER UNIDENTIFIED COMPONENTS.

Waste Disposal Methods:CONSULT LOCAL AUTHORITIES.DISPOSAL MUST BE MADE
IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.